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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 44, 2014 - Issue 7
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Original Articles

Two Manganese(II) Supramolecular Complexes Based on Imidazole Dicarboxylates: Syntheses, Crystal Structures, and Properties

Jie Li College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, Henan, P. R. China
,
Beibei Guo College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, Henan, P. R. China
,
Shaofeng Liu College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, Henan, P. R. China
&
Gang Li College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, Henan, P. R. China
Pages 1041-1049 | Received 29 Mar 2013, Accepted 11 Apr 2013, Published online: 04 Mar 2014
 
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Abstract

Two novel Mn(II) complexes [Mn(MDPhH2IDC)2(H2O)2] n (1) (MDPhH3IDC = 2-(3,4-methylenedioxyphenyl)-1H-imidazole-4, 5-dicarboxylic acid), [Mn( m-CPhH3IDC)2(H2O)2] n (2) (m-CPh H4IDC = 2-(3-carboxylphenyl)-1H-imidazole-4,5-dicarboxylic acid) have been hydrothermally synthesized with two kinds of imidazole dicarboxylate ligands, respectively, and structurally characterized by elemental analyses, IR spectra, as well as single crystal X-ray diffraction analysis. The 3D solid-state supramolecular structures of the complexes involve intermolecular hydrogen bonds. Furthermore, the thermal and photoluminescent properties of the complexes have been investigated.

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