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Original Articles

Preparation of Honeycomb Magnetic Co3O4 Nanostructures from Trans, Trans, Trans-[Co(py)2(H2O)2(SCN)2] as a New Precursor

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Pages 74-79 | Received 21 May 2013, Accepted 11 Jun 2013, Published online: 02 Sep 2014
 

Abstract

Co3O4 nanostructures were synthesized via a facile thermal treatment method by using the trans, trans, trans-[Co(py)2(H2O)2(SCN)2] as a new precursor. In synthetic process Co-complex was synthesized by reaction of KSCN via trans, trans, trans-[Co(py)2(H2O)2(NO3)2]. Results show that changing on temperature to 400°C caused to preferential growth and formation of the honeycomb nanostructures. Nanostructures were characterized by scanning electron microscope, X-ray diffraction, UV–visible, Fourier transformed infrared spectroscopy and alternating gradient force magnetometer. It's found that the Co3O4 nanostructures exhibit a ferromagnetic behavior with a saturation magnetization of 16.6 emu/g and a coercivity of 251.4 Oe at room temperature.

Additional information

Funding

The authors are grateful to council of University of Kashan by Grant No (159271/77) and Isfahan University of Technology (IUT) for providing financial support to undertake this work.

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