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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 45, 2015 - Issue 4
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Original Articles

Synthesis and Characterization of Two Copper (II) Complexes of 4′-tolyl-2,2′:6′,2″-Terpyridine and Simultaneous Detection and Separation of [Cu(ttpy)(NO3)2] and CuO by Capillary Zone Electrophoresis Method

Lotf Ali SaghatforoushDepartment of Chemistry, Payame Noor University, Tehran, I. R. IranCorrespondence[email protected]
View further author information
,
Ertan ŞahinAtatürk University, Department of Chemistry, Erzurum, TurkeyView further author information
,
Robabeh MehdizadehDepartment of Chemistry, Payame Noor University, Tehran, I. R. IranView further author information
,
Mohammad HasanzadehDrug Applied Research Center, Research Student Committee, Tabriz University of Medical Sciences, Tabriz, I. R. IranView further author information
,
Soheila SanatiDepartment of Chemistry, Payame Noor University, Tehran, I. R. IranView further author information
&
Seyed Javad MuseviDepartment of Chemistry, Shahid Beheshti Technical Faculty, Technical and Vocational University, Urmia, I. R. IranView further author information
Pages 597-604 | Received 30 May 2013, Accepted 27 Jul 2013, Published online: 15 Sep 2014
 
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Abstract

A simple synthetic method has been used to prepare copper(II) complexes of 4′-tolyl-2,2′:6′,2″-terpyridine (ttpy) ligand, [Cu(ttpy)(NO3)2] (1) and [Cu2(ttpy)(ClO4)4]n (2), in good yields. Also capillary zone electrophoresis (CZE) method was used for simultaneous detection and separation of complex 1 and CuO obtained from its calcination.

Additional information

Funding

Support of this investigation by Payame Noor University and Atatürk University, Erzurum, Turkey, is gratefully acknowledged.

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