Abstract
A novel 63-nets framework {[Cd(SiF6)(C11H10N2)2]·(CH2Cl2)·(H2O)}n (1) was generated based on asymmetric ligand 3-(pyridin-4-yl)benzenamine (L). L acts as a bidentate ligand to link Cd(II) centers into a 63-nets topology with rectangular channels encapsulating dichloromethane and water as guest molecules. In addition, their luminescent properties were investigated primarily in the solid state, which is basically related to its incorporation into the metal-containing complexes. The result displays that the choice of the amino-functionalized pyridine-containing ligand leading to special connection patterns and diversity of the hydrogen bonds plays a crucial role in the construction of the novel topological framework with interesting luminescent property.
Supplementary Material
934665 (1) contains the supplementary crystallographic data for this paper. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: (+44)1223–336-033; e-mail: [email protected]).