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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 45, 2015 - Issue 6
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Original Articles

Three-Fold Interpenetrated CdSO4 Topology in a Co(II) Coordination Polymer Constructed From Pamoic Acid and N-Containing Auxiliary Ligand

Hui GaoDepartment of Environmental Engineering and Chemistry, Luoyang Institute of Science and Technology, Luoyang, P. R. China
,
Xin-Hua LouCollege of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, P. R. ChinaCorrespondence[email protected]
,
Qiao-Tong LiCollege of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, P. R. China
,
Wen-Jun DuCollege of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, P. R. China
&
Chen XuCollege of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, P. R. China
Pages 865-868 | Received 05 Aug 2013, Accepted 08 Sep 2013, Published online: 04 Sep 2014
 
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Abstract

A new Co(II) compound, namely [Co(pam)(bpa)(H2O)2]n n(DMF) (1 H2pam = pamoic acid, bpa = 1,2-di(4-pyridyl)ethylene, DMF = N, N’-dimethylformamide), has been successfully synthesized and structurally characterized. Single-crystal X-ray analysis reveals that 1 is a 3-fold interpenetrated three-dimensional (3D) framework. Topological analysis shows that this compound can be simplified into a four-connected CdSO4 topological network. TG analysis reveals that compound 1 can be stable up to 316ºC.

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