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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 45, 2015 - Issue 7
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Original Articles

Synthesis, Crystal Structure, Properties, and Theoretical Study of CdI2(phen)2 (phen = 1,10-phenanthroline)

Wen-Tong ChenInstitute of Applied Chemistry, School of Chemistry and Chemical Engineering, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, Ji’an, Jiangxi, P. R. China;State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, P. R. ChinaCorrespondence[email protected]
,
Zhong-Liang YaoBiology and Chemistry Engineering Department, Fuqing Branch of Fujian Normal University, Fuqing, Fujian, P. R. China
,
Han-Mao KuangInstitute of Applied Chemistry, School of Chemistry and Chemical Engineering, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, Ji’an, Jiangxi, P. R. China
,
Hua-Long ChenInstitute of Applied Chemistry, School of Chemistry and Chemical Engineering, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, Ji’an, Jiangxi, P. R. China
&
Zhi-Gang LuoInstitute of Applied Chemistry, School of Chemistry and Chemical Engineering, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, Ji’an, Jiangxi, P. R. China
Pages 952-955 | Received 18 Oct 2013, Accepted 02 Nov 2013, Published online: 09 Mar 2015
 
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Abstract

A cadmium compound CdI2(phen)2, (1) (phen = 1,10-phenanthroline), was been synthesized via a hydrothermal reaction and structurally characterized by single-crystal X-ray diffraction. The cadmium ion is coordinated by two terminal iodine ions and four nitrogen atoms from two coordinating phen molecules, constructing a distorted octahedron. Compound 1 features an isolated structure. Photoluminescent study shows that compound 1 exhibits a strong and broad emission in the blue region. Theoretical investigation reveals that the emission can be attributed to ligand to ligand charge transfer.

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