Advanced search
Publication Cover
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 46, 2016 - Issue 2
Submit an article Journal homepage
187
Views
3
CrossRef citations to date
0
Altmetric
Original Articles

Synthesis and Crystal Structure of an Iron(II) Complex With Nitronyl Nitroxides

Xiaoling WangDepartment of Chemistry and Chemical Engineering, Anhui Key Laboratory of Low Temperature Co-Fired Materials, Huainan Normal University, Huainan, P. R. ChinaCorrespondence[email protected]
,
Guilin WenDepartment of Chemistry and Chemical Engineering, Anhui Key Laboratory of Low Temperature Co-Fired Materials, Huainan Normal University, Huainan, P. R. China
,
Fengwu WangDepartment of Chemistry and Chemical Engineering, Anhui Key Laboratory of Low Temperature Co-Fired Materials, Huainan Normal University, Huainan, P. R. China
,
Yonghong ChenDepartment of Chemistry and Chemical Engineering, Anhui Key Laboratory of Low Temperature Co-Fired Materials, Huainan Normal University, Huainan, P. R. China
,
Xing ZhaoDepartment of Chemistry and Chemical Engineering, Anhui Key Laboratory of Low Temperature Co-Fired Materials, Huainan Normal University, Huainan, P. R. China
&
Xia BaoDepartment of Chemistry and Chemical Engineering, Anhui Key Laboratory of Low Temperature Co-Fired Materials, Huainan Normal University, Huainan, P. R. China
Pages 206-209 | Received 17 Feb 2014, Accepted 23 Aug 2014, Published online: 29 Sep 2015
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

An iron(II) complex with nitronyl nitroxides, [FeII(NIT4Py)2(N(CN)2)2(H2O)2] (NIT4Py = 2-(4′-pyridyl)- 4,4,5,5-tetramethylimidazoline-1-oxyl 3-oxide), was synthesized and characterized by X-ray diffraction analysis, elemental analyses, and IR spectrum. X-ray analysis reveals that the center Fe(II) ion is six-coordinated with a slightly distorted octahedral geometry. The adjacent monomeric entities are linked by hydrogen bonds to generate a 3D structure.

Funding

This work was financially supported by Natural Science Foundation of Anhui Province (Grant Nos. 1408085QB23 and 1308085QB36), National Science Foundation of China (Grant No. 21301062) and Scientific Research Start-Up Fund of Huainan Normal University.

Supplementary Material

Crystallographic data for the structural analysis of the complex have been deposited in the Cambridge Crystallographic Center (deposition No. CCDC 846692). Copies of the information may be obtained free of charge from the director, CCDC, 12 Union Road, Cambridge, CB2 1EZ, UK (fax: +44-1223-336033; e-mail: [email protected] or www: http://www.ccdc.cam.ac.uk).

Log in via your institution

Access through your institution

Log in to Taylor & Francis Online

Restore content access

Restore content access for purchases made as guest
Purchase options * Save for later

PDF download + Online access

  • 48 hours access to article PDF & online version
  • Article PDF can be downloaded
  • Article PDF can be printed
USD 61.00 Add to cart

Issue Purchase

  • 30 days online access to complete issue
  • Article PDFs can be downloaded
  • Article PDFs can be printed
USD 674.00 Add to cart

* Local tax will be added as applicable

Related Research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.