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Original Articles

Effect Ancillary Ligands on the Zn(II) Complexes: Syntheses, Structure, and Luminescence

, , , &
Pages 1647-1651 | Received 04 Feb 2015, Accepted 27 Dec 2015, Published online: 05 Apr 2016
 

Abstract

Two Zn-based complexes, namely {[Zn(L3)(2,2′-bipy)(H2O)2]n·L3} (1), and [Zn(L3)2(phen)(H2O)] (2) (HL3 = 3-(4-hydroxyphenyl)propanoic acid, 2,2′-bipy = 2,2′-bipyridine and phen = 1,10-phenanthroline), have been synthesized and structurally characterized by single-crystal diffraction analysis. Both 1 and 2 have mononuclear units, which are further linked into different 2D layers via the hydrogen bond interactions. Furthermore, the luminescent and stable properties of 1–2 are also discussed.

Funding

The authors acknowledge financial assistance from Sichuan University of Science and Engineering (nos. 2014PY01 and 2015PY03), and the Education Committee of Sichuan Province (no. 12ZA090, 14ZB0220, 15ZB0222, 15ZB0214).

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