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Inorganic and Nano-Metal Chemistry Volume 47, 2017 - Issue 2
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Articles

Two quinazolinone-2-carboxylic acid copper(II) complexes synthesized by 4(3H)-quinazolinone-2-ethylformate high-temperature hydrolysis: Fluorescent and anticancer activity

B.-L. LiaoCollege of Chemistry and Biological Engineering, Hechi University, Yizhou, Guangxi, P. R. China;College of Chemistry and Pharmacy, Guangxi Normal University, Guilin, Guangxi, P. R. China
,
S.-X. LiCollege of Chemistry and Biological Engineering, Hechi University, Yizhou, Guangxi, P. R. China;College of Chemistry and Pharmacy, Guangxi Normal University, Guilin, Guangxi, P. R. ChinaCorrespondence[email protected]
,
P. LuoCollege of Chemistry and Pharmacy, Guangxi Normal University, Guilin, Guangxi, P. R. China
&
Y.-M. JiangCollege of Chemistry and Pharmacy, Guangxi Normal University, Guilin, Guangxi, P. R. China
Pages 213-217 | Received 15 Apr 2015, Accepted 30 Jan 2016, Published online: 27 May 2016
 
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ABSTRACT

Two novel copper(II) complexes of quinazolinone-2-carboxylic acid were synthesized by 4(3H)-quinazolinone-2-ethylformate high-temperature hydrolysis and characterized by single-crystal X-ray diffraction, IR spectroscopy, elemental analysis, and solid-state fluorescence. Meanwhile, 1 was also tested for anticancer activity. By 4(3H)-quinazolinone-2-ethylformate high-temperature hydrolysis, we successfully avoided carboxyl decarboxylated, to synthesis of high-temperature easily decarboxylation complexes had a guiding role.

Funding

The authors acknowledge the financial support from the Guangxi Natural Science Foundation (No. 2014GXNSFAA118035), the Scientific Research and Technological Development Project of Guilin (NO.20110330), and the Guangxi Natural Science Foundation (No. 200807MS090), andGuangxi Zhuang Autonomous Region Department of Education Science Research Project (NO.YB2014331).

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