ABSTRACT
A new complex [Ni(H1.5bhbm)2(AcO)]·11H2O (1) (H2bhbm = [(5-Bromo- 2-hydroxy-benzylidene)-amino]-methanesulfonic acid) was synthesized, and its structure was determined by elemental analysis, X-ray diffraction analysis, and Hirschfeld surface analysis. The crystal belongs to hexagonal system, space group R-3. The Ni(II) ion is coordinated by two N atoms and four O, atoms forming a distorted octahedral environment. A supra-water network was formed through abundant O-H···O hydrogen bonds. According to the 3D Hirschfeld surface and 2D fingerprint plots, the main interactions in 1 are the H···H, O···H, Br···H and Br···Br contacts.
Funding
This work was financially supported by the National Nature Science Foundation of China (No.21161006, 21274116), and Program of the first session backbone teacher of Guangxi.