Synthesis, crystal structure, and luminescent property of a Cu (II) coordination polymer based on benzene-1,2-dicarboxylic acid and 1,2-bis(pyridine-3-ylmethoxy)benzene

ABSTRACT

A new coordination polymer, [Cu(L)(bpmb)]_n (I) (L = benzene-1,2-dicarboxylic acid, bpmb = 1,2-bis(pyridine-3-ylmethoxy)benzene), has been hydrothermally synthesized and characterized by single X-ray diffraction, IR, element analysis, and thermal analysis. The compound I shows a two-dimensional corrugated sheet with 4⁴6² topology. In addition, the luminescent property of I is investigated.

KEYWORDS:

• Copper(II) coordination polymer
• crystal structure
• 1,2-bis(pyridine-3-ylmethoxy)benzene
• benzene-1,2-dicarboxylic acid
• fluorescence

Funding

This work was supported by the National Natural Science Foundation of China (grant No. 21301010, 21401006 and U1304210).