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Inorganic and Nano-Metal Chemistry Volume 47, 2017 - Issue 4
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Articles

Synthesis and characterization of 4-chlorobutyl ester of 5-(8-carboxyl-1-naphthyl)-10,15,20-triphenyl-porphyrin and its zinc complex

Huan LiuKey Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, P. R. China
,
Caifen OuKey Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, P. R. China
,
Ben MaKey Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, P. R. China
&
Chuanjiang HuState and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, P.R. ChinaCorrespondence[email protected]
Pages 597-602 | Received 26 May 2015, Accepted 09 Jul 2016, Published online: 11 Aug 2016
 
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ABSTRACT

In the presence of Brønsted–Lowry acids (phenol or dry HCl), the acyl chloride, which was obtained by the reaction between 5-(8-carboxyl-1-naphthyl)-10,15,20-triphenyl-porphyrin (CNTPP) and oxalyl chloride, reacted with tetrahydrofuran and led to the 4-chlorobutyl ester, P1, as the result of the acylative cleavage. P1 and its zinc complex [ZnP1] have been characterized by 1H NMR. The structure of [ZnP1] was obtained by X-ray crystallography. Zinc is coordinated by four pyrrole nitrogens. The 8-position substituent, a 4-chlorobutyl ester group, lies above the porphyrin plane.

Funding

This work was supported by the Natural Science Foundation of China (No. 20971093 and 21271133) and the Priority Academic Program Development of Jiangsu Higher Education Institutions.

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