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Articles

Ruthenium(II) complexes with 8-(diphenylphosphino)quinoline: Synthesis, spectroscopic properties, and single-crystal X-ray structures

, , &
Pages 655-660 | Received 10 Nov 2015, Accepted 09 Jul 2016, Published online: 11 Aug 2016
 

ABSTRACT

This work describes the synthesis and characterization of two new ruthenium(II) complexes with 8-diphenylphosphinoquinoline (N-P). The complexes [Ru(N-P)(DMSO)2Cl2] (1), where DMSO = dimethyl sulfoxide, and [Ru(N-P)2Cl2] (2) were characterized by FT-IR, UV-Vis spectrometer, and X-ray crystallography. Single-crystal X-ray structures of (1) and (2), which crystallize in the triclinic space group P-1 and orthorhombic space group Pbca, respectively, have been determined. The X-ray structural analyses of both complexes indicate that the geometries around the Ru center are distorted octahedral. Bond length analysis indicates a trans influence in the order: P > N > S > Cl.

Funding

The authors gratefully acknowledge the financial support provided by the Deanship of Academic Research (Project No. 1331), The University of Jordan, Amman 11942, Jordan.

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