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Energy Sources, Part A: Recovery, Utilization, and Environmental Effects Volume 33, 2010 - Issue 1
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Original Articles

A Model of Solubility of Hydrogen in Hydrocarbons and Coal Liquid

H. Luo College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan, P.R. China
,
K. Ling College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan, P.R. China
,
W. Zhang College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan, P.R. China
,
Y. Wang College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan, P.R. China
&
J. Shen College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan, P.R. China
Pages 38-48 | Received 02 Apr 2010, Accepted 23 Apr 2010, Published online: 05 Oct 2010
 
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Abstract

The experimental devices were established using a vapor-liquid phase equilibrium sampling method. The solubility of hydrogen in the model components of coal liquid, such as hexadecane, methylbenzene, 1,2,3,4-tetrahydronaphthalene, naphthalene, quinoline, and 1-naphthol, was measured. A mathematical model based on Pierotti method and Henry law is proposed. The expression of the model is

in which related parameters in the model are obtained by regression of known solubility data for different solvents. Using the model, the literature data of hydrogen solubility were regressed, and related parameters and mathematical expressions were obtained. The average absolute deviation between regression values and experimental results is 1.4–5%.

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