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Journal of Sulfur Chemistry Volume 25, 2004 - Issue 6
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Original Articles

An expedient synthesis of methyl vinyl sulfide from dimethyl disulfide and acetylene

Boris A. Trofimov A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Street, Irkutsk, 664033, Russia
,
Ludmila A. Oparina A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Street, Irkutsk, 664033, RussiaCorrespondence[email protected]
,
Nina K. Gusarova A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Street, Irkutsk, 664033, Russia
,
Nataliya A. Belogorlova A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Street, Irkutsk, 664033, Russia
,
Nataliya A. Chernysheva A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Street, Irkutsk, 664033, Russia
,
Nina I. Ivanova A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Street, Irkutsk, 664033, Russia
,
Lidiya N. Parshina A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Street, Irkutsk, 664033, Russia
&
Jochem Henkelmann BASF Aktiengesellschaft, Ammonia Laboratory, Ludwigshafen, Germany
 show all
Pages 395-399 | Received 20 Sep 2004, Accepted 29 Sep 2004, Published online: 21 Aug 2006
 
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Abstract

Dimethyl disulfide reacts with acetylene under atmospheric pressure in basic reductive systems MOH (M=Na, K)–N2H4 · H2O–N-methylpyrrolidone and Na2S · 9H2O–N2H4 · H2O–N-methylpyrrolidone to form methyl vinyl sulfide in up to 79% yield.

Acknowledgment

Financial support from the Ministry of Industry, Science and Technologies of the Russian Federation (grant No. NSH-2241.2003.3) is gratefully acknowledged.

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