Advanced search
Publication Cover
Journal of Sulfur Chemistry Volume 42, 2021 - Issue 6
Submit an article Journal homepage
254
Views
5
CrossRef citations to date
0
Altmetric
Research Article

A novel practical preparation of methyl methanethiosulfonate from dimethyl sulfoxide initiated by a catalytic amount of (COCl)2 or anhydrous HCl

Shuai HuangBeijing Advanced Innovation Center for Food Nutrition and Human Health, Beijing Key Laboratory of Flavor Chemistry, Beijing Technology and Business University, Beijing, People’s Republic of ChinaView further author information
,
Hao WangBeijing Advanced Innovation Center for Food Nutrition and Human Health, Beijing Key Laboratory of Flavor Chemistry, Beijing Technology and Business University, Beijing, People’s Republic of ChinaView further author information
,
Yongguo LiuBeijing Advanced Innovation Center for Food Nutrition and Human Health, Beijing Key Laboratory of Flavor Chemistry, Beijing Technology and Business University, Beijing, People’s Republic of ChinaView further author information
,
Baoguo SunBeijing Advanced Innovation Center for Food Nutrition and Human Health, Beijing Key Laboratory of Flavor Chemistry, Beijing Technology and Business University, Beijing, People’s Republic of ChinaView further author information
,
Hongyu TianBeijing Advanced Innovation Center for Food Nutrition and Human Health, Beijing Key Laboratory of Flavor Chemistry, Beijing Technology and Business University, Beijing, People’s Republic of ChinaCorrespondence[email protected]
View further author information
&
Sen LiangBeijing Advanced Innovation Center for Food Nutrition and Human Health, Beijing Key Laboratory of Flavor Chemistry, Beijing Technology and Business University, Beijing, People’s Republic of ChinaView further author information
Pages 604-613 | Received 13 Apr 2021, Accepted 16 May 2021, Published online: 30 May 2021
 
Sample our Engineering & Technology journals, sign in here to start your access, latest two full volumes FREE to you for 14 days

Abstract

A novel practical preparation method for methyl methanethiosulfonate (MMTS) has been developed. Dimethyl sulfoxide was converted to MMTS in the presence of a catalytic amount of oxalyl chloride or anhydrous HCl in acetonitrile under reflux in an ideal yield. Methanesulfenic acid was proposed to be the key intermediate for the formation of MMTS.

GRAPHICAL ABSTRACT

Disclosure statement

No potential conflict of interest was reported by the author(s).

Additional information

Funding

Financial support from the National key research and development program [grant numbers 2017YFB0307502, 2016YFD0400801].

Log in via your institution

Access through your institution

Log in to Taylor & Francis Online

Restore content access

Restore content access for purchases made as guest
Purchase options * Save for later

PDF download + Online access

  • 48 hours access to article PDF & online version
  • Article PDF can be downloaded
  • Article PDF can be printed
USD 61.00 Add to cart

Issue Purchase

  • 30 days online access to complete issue
  • Article PDFs can be downloaded
  • Article PDFs can be printed
USD 683.00 Add to cart

* Local tax will be added as applicable

Related Research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.