Unraveling the permeation-enhancing effect of didecyl dimethyl ammonium chloride (DDAC) on poplar wood (Populus cathayana Rehd.)

ABSTRACT

Wood is a sustainable, porous material with a diverse range of applications. However, the low permeability of liquids within wood poses significant challenges for the widespread application of advanced wood-based materials such as oil–water separation, as well as traditional chemical modification processes of wood. Surfactants exhibit potential to improve permeability of liquids within wood by effectively enhancing liquid wettability on solid surfaces. In this study, the effects of didecyl dimethyl ammonium chloride (DDAC) on liquid absorption of water and copper ethanolamine (CE) by wood were explored under atmospheric temperature and pressure. With an increase in concentration of DDAC, its promotion effect on liquid absorption of wood became more pronounced. The most notable enhancement was observed in wicking test where 0.10% DDAC increased liquid absorption of wood to water by 156.7% and to CE by 65.5%. The enhancement of liquid wettability on wood surface cannot be solely attributed to reduction of liquid surface tension, the adsorption of DDAC onto wood surface also plays a crucial role in this process. This study investigated the intrinsic mechanisms by which DDAC enhanced the permeability of liquids within wood, contributing to increased productivity and reduced energy consumption.

GRAPHICAL ABSTRACT

KEYWORDS:

• Liquid permeability
• wood
• DDAC
• wetting

Disclosure statement

No potential conflict of interest was reported by the author(s).

CRediT authorship contribution statement

Runhua Zhang: Methodology, Validation, Investigation, Data curation, Visualization, Formal analysis, Writing – original draft; Jiajia Xu: Resources, Investigation; Mingchang Zhang: Methodology; Zhenxin Zhang: Investigation; Erni Ma: Supervision, Writing – review and editing; Jinzhen Cao: Conceptualization, Writing – review and editing, Methodology, Validation, Supervision, Project administration, Funding acquisition.

Additional information

Funding

This work was financially supported by the National Key Research and Development Program of China (2023YFD2200502).