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ORIGINAL PAPER

Tritium Isotope Separation by Water Distillation Column Packed with Silica-gel Beads

Pages 619-623 | Received 16 Jan 2004, Accepted 12 Mar 2004, Published online: 07 Feb 2012
 

Abstract

Tritium enrichment or depletion by water distillation was investigated using a glass column of 32 cm in height packed with silica-gel beads of 3.4mm in average diameter. The total separation factor of the silica-gel distillation column, αH-T—, was compared with those of an open column distillation tower and of a column packed with stainless-steel Dixon rings. Depletion of the tritium activity in the distillate was enhanced by isotopic exchange with water adsorbed on silica-gel beads that have a higher affinity for HTO than for H2O. The value of alphaH-T-1 of the silica-gel distillation column was about four times larger than that of a column without any packing and about two times larger than that of the Dixon-ring column. The improvement of αH-T by the silica-gel adsorbent indicated that the height of the distillation-adsorption column becomes shorter than that of the height of conventional distillation columns.

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