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ARTICLE

Zinc Isotope Fractionation on Benzo-15-crown-5 Resin by Liquid Chromatography

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Pages 623-627 | Received 21 Jul 2006, Accepted 22 Jan 2007, Published online: 05 Jan 2012
 

Abstract

Chromatographic fractionation of zinc isotopes was performed on the synthesized benzo-15-crown-5 resin as a column packing material at 323K in the breakthrough manner for both a frontal and a rear bands. Zinc adsorption capacity was affected by anion chloride concentration and solvent dielectric constant. The heavier zinc isotopes were found enriched to the solution phase and the lighter zinc isotope was concentrated on the resin phase. The frontal maximum enrichment ratio for isotopic pair of 68Zn/64Zn was 1.0081. The isotope separation coefficients for isotopic pair of 68Zn/64Zn for frontal and rear band, were 5.3 × 10−4, 4.5 × 10−4, respectively.

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