Study of carbon aerogel-activated carbon composite electrodes for capacitive deionization application

Abstract

Electrodes synthesized using mesoporous carbon aerogel (CA), microporous-activated carbon (AC), and different combinations of the two were evaluated for capacitive deionization application. Composite electrodes with CA and AC in the ratio of 75:25 provided the highest specific capacitance value (90 F/g at scan rate of 2 mV/s). Further, it was observed that on increasing the scan rates to up to 10 mV/s, the reduction in specific capacitance values for the electrodes with 75:25 CA/AC composition was only 5%, whereas the reduction for pure CA and pure AC electrodes were 23 and 52%, respectively. The test cell made using 75:25 CA/AC composite electrodes (size 10 cm × 10 cm with material loading of 15 mg/cm²) showed fast adsorption and desorption cycle of ∼15 min and salt removal efficiency of 51% was obtained.

Keywords:

• Carbon aerogel
• Activated carbon
• Cyclic voltammetry
• Capacitive deionization

Acknowledgment

We would like to thank Shri Gopal Mohod for his help at various stages to carry out desalination experiments.