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Articles

Kinetics and thermodynamics of efficient phosphorus removal by a complex material

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Pages 1949-1954 | Received 23 Nov 2013, Accepted 01 Aug 2014, Published online: 03 Sep 2014
 

Abstract

In this paper, we investigated the kinetics and thermodynamics of phosphorus adsorption by a new efficient phosphorus removal composite (EPRC). Kinetic analysis showed that the adsorption of phosphorus by EPRC is best described by a pseudo-first-order equation. Thermodynamic analysis showed that the Gibbs free energy (ΔG°) is negative, implying that the reaction is spontaneous. Moreover, the change in enthalpy (ΔH°) of phosphorus adsorption by EPRC was always greater than 60 kJ/mol, indicating that the adsorption was an endothermic chemical process. Furthermore, EPRC adsorbs phosphorus better at higher temperatures.

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