Synthesis of acrylic-acid-modified shorea sawdust and application in adsorbing toxic organic materials

Abstract

Shorea sawdust grafted with poly(acrylic acid) (SD-g-PAA) is synthesized and characterized as an adsorbent of toxic organic compounds. SD-g-PAA copolymers are prepared using Fenton’s reagent (Fe⁺²–H₂O₂) as the redox initiator. The graft copolymerization is examined to determine the effects of temperature, concentrations of and H₂O_2(aq), and AA/SD ratio. The obtained maximum grafting percentage of the grafted copolymer is 13.0 ± 0.2%. The grafted copolymer is characterized using Fourier transform infrared spectroscopy and solid-state ¹³C NMR. A representative SD-g-PAA copolymer is neutralized to a sodium salt (SD-g-PANa) and used in the adsorption of malachite green (MG), methyl violet (MV), and paraquat (PQ). The monolayer adsorption capacities of these substances are 233.7, 312.9, and 164.8 mg/g adsorbent, respectively. The high adsorption capacity of SD-g-PANa for toxic matter indicates its potential in the treatment of wastewater that contains MG, MV, or PQ.

Keywords:

• Acrylic acid
• Shorea sawdust
• Graft copolymerization
• Adsorption
• Toxic materials

Acknowledgments

The authors would like to thank Comlet Chem. Ind. Co. Ltd for supplying the raw materials.