Antibacterial properties of membranes modified by acrylic acid with silver nanoparticles

Abstract

Organic fouling is a very important problem in case of membrane filtration processes. Partially, impact of fouling might be overcome by: back puls, membrane cleaning, cross-flow filtration, or surface modification. In this paper, first, surface modification of membrane by acrylic acid and then silver nanoparticles will be presented. In the first step of modification, acrylic acid is grafted to the surface of the polypropylene capillary membrane, thanks to Fenton-type reaction. Then, membranes are further modified by the synthesis of silver nanoparticles directly on the membrane surface. It is well known that silver nanoparticles exhibit antibacterial properties for micro-organisms such as Escherichia coli and Bacillus subtilis. Also the presence of acrylic acid on the surface of the membrane should reduce adhesion of particles to the membrane surface. In the present work, results obtained for acrylic acid grafting will be presented including FT-IR analysis and the amount of grafted carboxylic groups. Results for membranes further modified by silver nanoparticles, as well as tests for antibacterial properties of such membranes, will be presented. Antibacterial properties of modified membranes were tested on two model gram positive and gram negative bacteria: E. coli and B. subtilis. Tests were performed in liquid and solid Lysogeny Broth. The presented membranes exhibit very good antibacterial/bacteriostatic properties.

Keywords:

• Membrane modification
• Fenton-type reaction
• Acrylic acid
• Silver
• Antibacterial

Acknowledgments

Authors would like to thank MSc. Jarosław Skowroński form the Institute for Sustainable Technologies—National Research Institute form Radom, Poland. This work was partially supported by the NCBiR project EraNet/MNT/NFSM/1/2011.

Notes

Presented at the MELPRO 2014 conference Membrane and Electromembrane Processes, 18–21 May 2014, Prague, Czech Republic