Iron oxide-impregnated dextrin nanocomposite: synthesis and its application for the biosorption of Cr(VI) ions from aqueous solution

Abstract

In this paper, iron oxide impregnated with dextrin (Dex-Fe₃O₄) nanocomposite was synthesized by simple one-step hydrothermal chemical precipitation reaction. The nanocomposite was characterized by XRD, FT-IR, TGA, DTG, SEM with EDX and TEM techniques. The material was further explored as an adsorbent for the removal of Cr(VI) ions from its aqueous solution. The optimum removal of Cr(VI) ions with the highest adsorption capacity of 17.8 mg g⁻¹ was observed at pH 2. The equilibrium data were analysed with Langmuir, Freundlich, D–R and Temkin isotherms model and data were best followed by Langmuir model and Temkin model with a maximum monolayer adsorption capacity of 51.28, 54.64, and 71.43 mg g⁻¹ at 30, 40, and 50°C, respectively. The activation energy calculated by D–R model reveals that the adsorption process is chemisorption in nature. The experimental data were best fitted with pseudo-second-order. The results of thermodynamic parameters (ΔG°, ΔH°, and ΔS°) showed that the adsorption of Cr(VI) on Dex-Fe₃O₄ is endothermic spontaneous in nature. The synthesized nanocomposite material is very promising for the removal of Cr(VI) from aqueous solution.

Keywords:

• Dex-Fe₃O₄
• TEM
• FT-IR
• Activation energy
• Endothermic

Acknowledgement

The authors gratefully acknowledge the instrumentation laboratory, centre for excellence in nanomaterials Department of applied physics AMU, Sophisticated Analytical instrumentation facility (SAIF) Punjab University Chandigarh and highly thankful to UGC-MANF Delhi for providing financial assistance.