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Analytical Chemistry Letters Volume 6, 2016 - Issue 4
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Original Articles

Cyclodextrin-Promoted Detection of Aromatic Toxicants and Toxicant Metabolites in Urine

Dana J. DiScenzaDepartment of Chemistry, University of Rhode Island, 51 Lower College Road, Kingston, Rhode Island02881, United States
,
Lauren GareauDepartment of Chemistry, University of Rhode Island, 51 Lower College Road, Kingston, Rhode Island02881, United States
,
Nicole SerioDepartment of Energy, Environmental Oversight Office, 15013 Denver West Parkway, Golden, Colorado80401, United States
,
John RoqueDepartment of Chemistry, University of Rhode Island, 51 Lower College Road, Kingston, Rhode Island02881, United States
,
Lindsey PrignanoDepartment of Chemistry, University of Rhode Island, 51 Lower College Road, Kingston, Rhode Island02881, United States
,
Molly VerderameDepartment of Chemistry, University of Rhode Island, 51 Lower College Road, Kingston, Rhode Island02881, United States
&
Mindy LevineDepartment of Chemistry, University of Rhode Island, 51 Lower College Road, Kingston, Rhode Island02881, United StatesCorrespondence[email protected]
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Pages 345-353 | Received 18 May 2016, Accepted 30 Jun 2016, Published online: 06 Oct 2016
 
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Abstract

Reported herein is the development of a fluorescence-based detection method for aromatic toxicants and toxicant metabolites in urine, using cyclodextrin-promoted energy transfer to high quantumyield fluorophores. This method distinguishes smoker urine from non-smoker urine, enables highly accurate analyte identification, and leads to micromolar detection limits.

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