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Original Articles

Syntheses, structures, and luminescence properties of two copper(I) thiocyanate coordination polymers with different N-donor ligands

, , , &
Pages 1248-1253 | Received 25 Sep 2016, Accepted 16 Jan 2017, Published online: 23 Mar 2017
 

ABSTRACT

Two coordination polymers, [Cu(SCN)(3-ptz)]n (1) and [Cu(SCN)(btmb)]n·nCH3CN (2) (3-ptz = 5-(3-pyridyl)tetrazole, btmb = 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene), were synthesized and characterized by EA, IR, PXRD and thermogravimetry. Complex 1 is a 2-D coordination polymer constructed from bidentate 3-ptz and 1,3-thiocyanate ligands. Complex 2 is a 2-D wave-like coordination polymer assembled by bidentate btmb and 1,3-thiocyanate ligands. Acetonitrile guest molecule is perched in the tunnel. Complexes 1 and 2 remain stable up to 240°C and 280°C, respectively. Complex 1 emits strong orange luminescence at 590 nm, and complex 2 emits blue luminescence at 468 nm.

Acknowledgments

This work was financially supported by the National Natural Science Foundation of China (21171115), and the Natural Science Foundation of Shanghai (17ZR1410600, 16ZR1411400).

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