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Inorganic and Nano-Metal Chemistry Volume 51, 2021 - Issue 3
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Article

An organic–inorganic hybrid nanoscale phosphotungstate with reactive oxygen species catalytic ability

Xiang Maa Chemistry and Chemical Engineering Department, Taiyuan Institute of Technology, Taiyuan, P. R. ChinaCorrespondence[email protected]
ORCID Iconhttps://orcid.org/0000-0001-7679-5741View further author information
ORCID Icon,
Yingjie Zhoua Chemistry and Chemical Engineering Department, Taiyuan Institute of Technology, Taiyuan, P. R. ChinaView further author information
,
Xinru Yuana Chemistry and Chemical Engineering Department, Taiyuan Institute of Technology, Taiyuan, P. R. ChinaView further author information
,
Yujie Miaoa Chemistry and Chemical Engineering Department, Taiyuan Institute of Technology, Taiyuan, P. R. ChinaView further author information
,
Qiang Zhaoa Chemistry and Chemical Engineering Department, Taiyuan Institute of Technology, Taiyuan, P. R. ChinaView further author information
,
Jiai Huaa Chemistry and Chemical Engineering Department, Taiyuan Institute of Technology, Taiyuan, P. R. China;b State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, P. R. ChinaCorrespondence[email protected]
ORCID Iconhttps://orcid.org/0000-0001-6005-149XView further author information
ORCID Icon &
Pengtao Mac Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan, P. R. ChinaCorrespondence[email protected]
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Pages 332-339 | Received 22 Feb 2020, Accepted 07 Jun 2020, Published online: 08 Jul 2020
 
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Abstract

An organic-inorganic hybrid polyoxometalate (POM) based on bi-nuclear copper complexes and Dawson-type phosphotungstate (POT) [CuL(H2O)][CuL]2[P2W18O62]·3H2O (abbreviated as CPW) (L = 2-(1H-pyrazol-3-yl)pyridine) was synthesized and structurally characterized by IR spectrum, and single-crystal X-ray diffraction. Structural analysis indicated that CPW is nanoscale molecule and extends into a two-dimensional layer, in which three bi-nuclear copper complexes are substituted at different sites of Dawson-type POT and joined adjacent POT fragments together. Notably, CPW can efficiently catalyze the production of reactive oxygen species.

Disclosure statement

No potential conflict of interest was reported by authors.

Additional information

Funding

This work was supported by the Natural Science Foundation of China (Grants 21573056), Shanxi Province Science Foundation for Youths (Grants 201901D211453), the Research Foundation for Advanced Talents of Shanxi Province (1800008001), the Research Foundation of Taiyuan Institute of Technology (03000352), and the Research Foundation of the Chinese State Key Laboratory of Coordination Chemistry (SKLCC1912).

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