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Inorganic and Nano-Metal Chemistry Volume 52, 2022 - Issue 7
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Articles

Crystal structure, IR, TG, and magnetic properties of a thiabendazole aqua-cobalt(II) 4,4'-stilbenedicarboxylate

Jia-Jun WangKey Laboratory of Preparation and Application of Environmental Friendly Materials, Ministry of Education, Jilin Normal University, Changchun, People’s Republic of China
,
Xue ChenKey Laboratory of Preparation and Application of Environmental Friendly Materials, Ministry of Education, Jilin Normal University, Changchun, People’s Republic of China
,
Bao-Sheng ZhangKey Laboratory of Preparation and Application of Environmental Friendly Materials, Ministry of Education, Jilin Normal University, Changchun, People’s Republic of China
,
Li-Nan DunKey Laboratory of Preparation and Application of Environmental Friendly Materials, Ministry of Education, Jilin Normal University, Changchun, People’s Republic of China
,
Meng-Yue XuKey Laboratory of Preparation and Application of Environmental Friendly Materials, Ministry of Education, Jilin Normal University, Changchun, People’s Republic of China
,
He WangKey Laboratory of Preparation and Application of Environmental Friendly Materials, Ministry of Education, Jilin Normal University, Changchun, People’s Republic of China
&
Chuan-Bi LiKey Laboratory of Preparation and Application of Environmental Friendly Materials, Ministry of Education, Jilin Normal University, Changchun, People’s Republic of ChinaCorrespondence[email protected]
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Pages 1012-1018 | Received 08 Sep 2020, Accepted 25 Nov 2021, Published online: 08 Feb 2022
 
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Abstract

A new coordination polymer, [Co(SDA)(TBZH)(H2O)]n (1, SDA = trans-4,4'-stilbenedicarboxylic acid tetra-anion, TBZH = thiabendazole) has been synthesized under hydrothermal condition. The structure has been determined by X-ray diffraction, thermal gravimetric analysis (TG), infrared spectrum (IR) and Magnetic properties. The structure of 1 contains one Co(II), the metal center Co(II) is five-coordinated and through the SDA, it bridged an infinite one-dimension chain. In TG curve, there are three weight loss steps and the residual may be CoO. The static and dynamic magnetic properties of the high-spin Co(II) polymer 1 were measured, there is no SCM properties exhibited by the polymer.

Acknowledgments

We thank the Project of the Education Department of Jilin Province, China (No. JJKH20180777KJ) and the Science and Technology Development Projects of Siping City (No. 2017057).

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