ABSTRACT
Plasticized PLA/PCL at various concentrations present in the results of DSC tests showed that the Tg and Tm shifted to a lower temperature and that the largest shift appeared at the 80PLA/20PCL–(TEC-PEG3)20. Plasticizers have been shown to enhance the crystallization of PLA. Rigid and plasticized blends have been shown to be partially miscible. The TGA results indicated that TEC and PEG3 promoted a decrease in thermal stability of the PLA and 80PLA/20PCL. The plasticizing effect was also shown by decrease in the dynamic storage modulus and viscosity of plasticized mixtures compared to the treated PLA and PLA/PCL.
Acknowledgments
The authors wish to acknowledge the Algerian Ministry of Higher Education and Scientific Research for supporting this work.
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Notes on contributors
Mounira Maiza
Dr. MAIZA Mounira obtained his PhD in Polymer Materials University from University of Setif, Algeria. He is now a Senior Researcher (B) at Research Center in Industrial Technologies -CRTI- Algeria. His research expertise is in Biomaterials and Polymers.
Abderrazak Hamam
Dr. HAMAM Abderrazak obtained his PhD in Chemical Engineering from University of Bejaia, Algeria; Academic accreditation Chemical Engineering from University of Setif, Algeria. He is now a Senior Researcher (A) at Research Center in Industrial Technologies -CRTI- Algeria. His research expertise is in nanomaterials for new energy technologies (electrocatalysis, photocatalysis, batteries, fuel cell, supercapacitors), Polymers, Biomaterials.