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Original Articles

DETERMINATION OF DISSOLVED IRON(II) AND IRON(III) IN WATER WITH 5-Br-PAN-S BY SOLID PHASE SPECTROPHOTOMETRY

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Pages 2169-2178 | Received 05 Mar 2001, Accepted 15 Jun 2001, Published online: 02 Feb 2007
 

Abstract

A very sensitive and selective method for the determination of trace amounts of iron(II) and iron(III) by SPS has been developed. It is based on the fixation of iron(II) as 1-(5-bromo-2-pyridylazo)-2-naphthol-6-sulphonic acid (5-Br-PAN-S) complex on a styrene-divinylbenzene anion-exchange resins. The absorbances of resin sorbed iron(II) complex is measured directly at 765 and 850 nm. Iron(III) was determined by difference measurements after reduction of iron(III) to iron(II) with hydroxylamine. The linear range of the determination is 0–25 μg for iron(II) or total iron. The detection limit for a sample volume of 100 ml using 0.5 g of anion-exchange, corresponds to 2.1 μgl−1. The method has been successfully applied to the determination of iron(II) and iron(III) in drinking water and natural waters.

ACKNOWLEDGMENTS

The authors are grateful to the Analysis and Testing Foundation of Zhejiang Province for providing financial support.

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