Abstract
A glucohexasaccharide, β‐d‐Glcp‐(1 → 3)‐[β‐d‐Glcp‐(1 → 3)‐β‐d‐Glcp‐(1 → 6)]‐β‐d‐Glcp‐(1 → 3)‐β‐d‐Glcp‐(1 → 3)‐β‐d‐Glcp was synthesized as its 4‐methoxyphenyl glycoside via 2 + 2 + 2 strategy with benzylidenated glucose mono‐ and disaccharides as the key intermediates.
Acknowledgments
This work was supported by The Chinese Academy of Sciences (KZCX3‐J‐08) and by The National Natural Science Foundation of China (Projects 30070185 and 39970864).