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Original Articles

SYNTHESIS AND BIOLOGICAL ACTIVITIES OF CYCLIC ADP-CARBOCYCLIC-RIBOSE AND ITS ANALOGS

, , , &
Pages 1355-1358 | Published online: 07 Feb 2007
 

Abstract

An efficient synthesis of cyclic ADP-carbocyclic-ribose (2), as a stable mimic for cyclic ADP-ribose, was achieved. Treatment of N 1-carbocyclic-ribosyla-denosine bisphosphate derivative 10 with AgNO3 in the presence of molecular sieves 3A in pyridine gave the desired cyclic product in 93% yield, which was deprotected to give the target cyclic ADP-carbocyclic-ribose (2).

ACKNOWLEDGEMENT

This investigation was supported in part by a Grant from the Ministry of Education, Science, Sports, and Culture of Japan.

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