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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 31, 2001 - Issue 3
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Original Articles

A SAFE AND EFFICIENT PROCEDURE TO PREPARE ALKYL AND ALKOXYALKYL CHLORIDES AND DICHLORIDES BY CATALYTIC DECOMPOSITION OF THE CORRESPONDING ALKYL AND ALKOXYALKYL CHLOROFORMATES AND BISCHLOROFORMATES WITH HEXABUTYLGUANIDINIUM CHLORIDE

Frédéric Violleau Laboratoire de Chimie Agro-industrielle, Ecole Nationale Supérieure des Ingénieurs en Arts Chimiques et Technologiques de Toulouse, Institut National Polytechnique de Toulouse, UMR 1010 INRA-INPT, 118, route de Narbonne, Toulouse Cedex 4, 31077, France
,
Sophie Thiébaud Laboratoire de Chimie Agro-industrielle, Ecole Nationale Supérieure des Ingénieurs en Arts Chimiques et Technologiques de Toulouse, Institut National Polytechnique de Toulouse, UMR 1010 INRA-INPT, 118, route de Narbonne, Toulouse Cedex 4, 31077, France
,
Elisabeth Borredon Laboratoire de Chimie Agro-industrielle, Ecole Nationale Supérieure des Ingénieurs en Arts Chimiques et Technologiques de Toulouse, Institut National Polytechnique de Toulouse, UMR 1010 INRA-INPT, 118, route de Narbonne, Toulouse Cedex 4, 31077, France
&
Pierre Le Gars SNPE, Chemin de la loge, Toulouse Cedex, 31078, France
Pages 367-373 | Received 23 Feb 2000, Published online: 09 Nov 2006
 
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Abstract

Small amounts of hexabutylguanidinium chloride (0.01 mol%) decomposes pure chloroformates or bischloroformates with different lengths of carbon chains by a semicontinuous process to diminish run-away risk, leading to chloride compounds with high yield and purity.

ACKNOWLEDGMENT

The authors thank SNPE for financial and technical support of this work.

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