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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 31, 2001 - Issue 13
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Original Articles

SILICA ACETATE COMPLEX OF N2O4: A HIGHLY EFFICIENT REAGENT FOR THE SELECTIVE CONVERSION OF THIOETHERS TO THEIR CORRESPONDING SULFOXIDES

, &
Pages 2037-2041 | Received 20 Jun 2000, Published online: 09 Nov 2006
 

Abstract

Complexation of gaseous N2O4 with acylated silica gel affords a molecular addition compound, which is a highly efficient oxidizing agent for the conversion of thioethers to sulfoxides.

ACKNOWLEDGMENT

We are grateful to Shiraz University Research Council for the partial support of this work.

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