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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 31, 2001 - Issue 13
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Original Articles

A COMPARATIVE STUDY OF SOME Pd-CATALYSED HECK REACTIONS IN POLAR- AND AQUEOUS BIPHASIC MEDIA

D. Bradley G. Williams Department of Chemistry and Biochemistry, Rand Afrikaans University, P.O. Box 524, Auckland Park, 2006, South AfricaCorrespondence[email protected]
,
Henriëtte Lombard Department of Chemistry and Biochemistry, Rand Afrikaans University, P.O. Box 524, Auckland Park, 2006, South Africa
&
Cedric W. Holzapfel Department of Chemistry and Biochemistry, Rand Afrikaans University, P.O. Box 524, Auckland Park, 2006, South Africa
Pages 2077-2081 | Received 19 Sep 2000, Published online: 09 Nov 2006
 
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Abstract

A comparative study of some Pd-catalysed reactions was carried out making use of various ligands and catalyst precursors in polar polar/aqueous biphasic media, the results of which assist in the judicious selection of the appropriate reaction conditions for such Heck reactions.

ACKNOWLEDGMENTS

We are indebted to SASOL, South Africa, for financial support of this work.

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