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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 31, 2001 - Issue 15
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Original Articles

DEHALOGENATION OF α-HALOCARBONYLS USING DECABORANE AS A TRANSFER HYDROGEN AGENT IN METHANOL

Seung Hwan Lee Graduate School of Biotechnology, Korea University, 1, 5-Ka, Anam-Dong, Sungbuk-Ku, Seoul, 136-701, S. Korea
,
Yeon Joo Jung Graduate School of Biotechnology, Korea University, 1, 5-Ka, Anam-Dong, Sungbuk-Ku, Seoul, 136-701, S. Korea
,
Young Jin Cho Graduate School of Biotechnology, Korea University, 1, 5-Ka, Anam-Dong, Sungbuk-Ku, Seoul, 136-701, S. Korea
,
Choon-Ock Maing Yoon Graduate School of Biotechnology, Korea University, 1, 5-Ka, Anam-Dong, Sungbuk-Ku, Seoul, 136-701, S. Korea
,
Han-Joon Hwang Graduate School of Biotechnology, Korea University, 1, 5-Ka, Anam-Dong, Sungbuk-Ku, Seoul, 136-701, S. Korea
&
Cheol Min Yoon Graduate School of Biotechnology, Korea University, 1, 5-Ka, Anam-Dong, Sungbuk-Ku, Seoul, 136-701, S. Korea
Pages 2251-2254 | Received 10 Jul 2000, Published online: 09 Nov 2006
 
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Abstract

Decaborane reduces α-halocarbonyl compounds to the corresponding dehalogenated products in the presence of Pd/C in methanol at room temperature efficiently and chemoselectively.

ACKNOWLEDGMENTS

This workwas supported by Korea Research Foundation (KRF-99-2000).

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