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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 31, 2001 - Issue 16
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Original Articles

POTENTIAL INTERMEDIATES FOR DITERPENOID QUINONES: CRYPTOTANSHINONE, TANSHINONE IIA, AND MILTIRONE

, , &
Pages 2471-2478 | Received 10 Nov 2000, Published online: 09 Nov 2006
 

Abstract

The transformation of the cyclic ethers (1) and (11) to dimethyl tetraol (8) and tetrahydrophenanthrene (14) respectively is described. These compounds proved to be a useful building block for the synthesis of angularly fused diterpenoid quinones.

ACKNOWLEDGMENT

The authors gratefully acknowledge the partial economic support from CONICIT to accomplish this work, which constitutes a part of the work of Project SI-98000387. We are grateful to Professor R.L. Danheiser, MIT, Cambridge for providing a copy of NMR spectra of tetraol.

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