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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 31, 2001 - Issue 16
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Original Articles

ULTRASONIC IRRADIATION AND THE HOMO- AND HETERO-DIELS-ALDER REACTION

Raul Alfaro Division of Earth and Physical Sciences, The University of Texas at San Antonio, 6900 N. Loop 1604 West, San Antonio, TX, 78249, U.S.A.
&
John V. McClusky Division of Earth and Physical Sciences, The University of Texas at San Antonio, 6900 N. Loop 1604 West, San Antonio, TX, 78249, U.S.A.
Pages 2513-2522 | Received 10 Nov 2000, Published online: 09 Nov 2006
 
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Abstract

The effects of ultrasound on the hetero- and homo-Diels- Alder reactions have been investigated varying ultrasonic source and solvent. Irradiation enhances both reactions minimally; however, while this appears to be due to cavitation in the homo Diels-Alder reaction, mechanical mixing appears to be the cause in the hetero-Diels-Alder reaction.

ACKNOWLEDGMENTS

This work was supported by awards from the Robert A. Welch Foundation, Research Corporation, and the University of Texas at San Antonio.

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