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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 31, 2001 - Issue 17
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Original Articles

ULTRASOUND ENHANCED PTC CONVERSION OF BENZAMIDE TO BENZONITRILE

Manickam Sivakumar Chemical Engineering Division, University Department of Chemical Technology (UDCT), University of Mumbai, Matunga, Mumbai, 400 019, India
,
Paramasivam Senthilkumar Chemical Engineering Division, University Department of Chemical Technology (UDCT), University of Mumbai, Matunga, Mumbai, 400 019, India
&
Aniruddha B. Pandit Chemical Engineering Division, University Department of Chemical Technology (UDCT), University of Mumbai, Matunga, Mumbai, 400 019, IndiaCorrespondence[email protected]
Pages 2583-2587 | Received 15 May 2000, Published online: 09 Nov 2006
 
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Abstract

Enhancement of the reaction rate by combining the beneficial effects of PTC and ultrasound has been explored in the present study by taking the transformation of benzamide by dehydration to give benzonitrile as a model system. It was found that there is a substantial reduction in the reaction time when ultrasound was coupled with PTC.

ACKNOWLEDGMENTS

MS gratefully acknowledges the Senior Research Fellowship (SRF), by the University Grants Commission, Government of India. The authors would also like to acknowledge the Department of Science and Technology (DST), Govt. of India, for the funding of this project.

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