ONE-POT SYNTHESIS OF THREE NOVEL FUNCTIONAL MONOMERS CONTAINING TWO ALLYLPHENOXY GROUPS AND ONE S-TRIAZINE RING

Abstract

Three novel functional monomers 2,4-di(2-allylphenoxy)-6-(2-naphthyloxy)-1,3,5-triazine (1), 2,4-di(2-allylphenoxy)-6-N,N-dimethylamino-1,3,5-triazine (2a), and 2,4-di(2-allylphenoxy)-6-N,N-diethylamino-1,3,5-triazine (2b) were prepared in one-pot by reacting cyanuric chloride with 2-allylphenol at first, and then by directly treating the adduct with 2-naphthol or Et₂NH (or Me₂NH) without separation. The structures of the monomers were characterized by FTIR, ¹H NMR and ¹³C NMR, and x-ray diffraction analysis of 1 was also carried out.

Keywords:

• Cyanuric chloride
• Functional monomers
• Triazine derivatives
• Heterocyclic compounds

ACKNOWLEDGMENT

The authors thank the National Ministry of Education of China for the financial support.