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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 32, 2002 - Issue 1
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Original Articles

CONVENIENT SYNTHESIS OF NOVEL 1,3,7-TRISUBSTITUTED BICYCLO[3.3.1]NONANE DERIVATIVES

Lada Klaić Department of Organic Chemistry and Biochemistry, Rudjer Bo[sbreve]ković Institute, P.O. Box 180, Zagreb, 10002, Croatia
,
Jelena Veljković Department of Organic Chemistry and Biochemistry, Rudjer Bo[sbreve]ković Institute, P.O. Box 180, Zagreb, 10002, Croatia
&
Kata Mlinarić-MajerskiCorrespondence[email protected]
Pages 89-97 | Received 28 Feb 2001, Published online: 21 Aug 2006
 
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ABSTRACT

Simple and efficient synthesis of several new 1,3,7-trisubstituted bicyclo[3.3.1]nonane derivatives [e.g. 1-hydroxybicyclo[3.3.1]nonane-3,7-dicarboxylic acid (4), dimethyl ester 1-hydroxybicyclo[3.3.1]nonane-3,7-dicarboxylic acid (5), di-methyl ester-1-methoxybicyclo[3.3.1]nonane-3,7-dicarboxylic acid (5a), 1-hydroxy-3,7-di(hydroxymethyl)bicyclo[3.3.1]nonane (6), 1-hydroxy-3,7-di(bromomethyl)bicyclo[3.3.1]nonane (7), 1-bromo-3,7-di(bromomethyl)bicyclo[3.3.1]nonane (8) and 1-bromo-3,7-di(cyanomethyl)bicyclo[3.3.1]nonane (9)] is described.

ACKNOWLEDGMENT

We thank the Ministry of Science and Technology (Grant P00980702) for financial support of this study.

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