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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 32, 2002 - Issue 3
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Original Articles

STEREOSELECTIVE SYNTHESIS OF SUBSTITUTED THIAZOLIDINE DERIVATIVES

Pushpa Pardasani Department of Chemistry, University of Rajasthan, Jaipur, 302 004, India
,
Ram T. Pardasani Department of Chemistry, University of Rajasthan, Jaipur, 302 004, India
,
Densely Sherry Department of Chemistry, University of Rajasthan, Jaipur, 302 004, India
&
Vivek Chaturvedi Department of Chemistry, University of Rajasthan, Jaipur, 302 004, India
Pages 435-441 | Received 19 Mar 2001, Published online: 16 Aug 2006
 
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ABSTRACT

Imines formed from a secondary cyclic amino acid and isatin afford thiazolo-oxazolidinone as the product via decarboxylative azomethine ylide formation. Subsequent 1,3-dipolar cycloaddition with dipolarophiles viz ethyl phenyl propiolate and methyl acrylate leads to novel spiro compounds. Structures and stereochemistry have been determined by detailed spectral and NOE studies.

ACKNOWLEDGMENT

We are thankful to CSIR, New Delhi for financial assistance.

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