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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 32, 2002 - Issue 6
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Original Articles

MICHAEL ADDITIONS OF ACTIVE METHYLENE COMPOUNDS TO CHALCONES PROMOTED BY SAMARIUM(III) IODIDE

Yongmin Ma Department of Chemistry, Zhejiang University, Xixi Campus, Hangzhou, 310028, P.R. China
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Yongmin Zhang Department of Chemistry, Zhejiang University, Xixi Campus, Hangzhou, 310028, P.R. China; Laboratory of Organometallic Chemistry, Chinese Academy of Sciences, Shanghai, 200032, P.R. China
Pages 819-823 | Received 17 Nov 2000, Published online: 16 Aug 2006
 
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ABSTRACT

Promoted by SmI3, α,β-unsaturated ketones reacted with malononitrile, ethylcyanoacetate, diethylmalonate, β-ketoester or nitromethane to give the 1,4-adducts in moderate to good yields.

ACKNOWLEDGMENT

We are grateful to the National Natural Science Foundation of China (Project No. 29872010) and the NSF of Zhejiang Province, China for financial support.

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