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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 32, 2002 - Issue 6
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Original Articles

FORMYLATION OF ARYL HALIDES CATALYZED BY A SILICA-SUPPORTED PHOSPHINE PALLADIUM COMPLEX

Ming-Zhong Cai Department of Chemistry, Jiangxi Normal University, Nanchang, P.R. China
,
Hong Zhao Department of Chemistry, Shangrao Teachers’ College, Shangrao, P.R. China
,
Jun Zhou Department of Chemistry, Jiangxi Normal University, Nanchang, P.R. China
&
Cai-Sheng Song Department of Chemistry, Jiangxi Normal University, Nanchang, P.R. China
Pages 923-926 | Received 30 Mar 2001, Published online: 16 Aug 2006
 
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ABSTRACT

The formylation of aryl bromides or iodides with sodium formate at atmospheric pressure of carbon monoxide readily proceeded in the presence of a silica-supported phosphine palladium complex in DMF to give the corresponding aldehydes in moderate to good yields.

ACKNOWLEDGMENT

This work was supported by the Natural Science Foundation of Jiangxi Province in China.

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