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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 32, 2002 - Issue 8
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Original Articles

HETEROGENEOUS CATALYZED REDUCTION OF POLYMER-BOUND NITROARENES

Martin Rödel Institut für Organische Chemie, Universität Regensburg, D-93040, Regensburg, Germany
,
Florian Thieme Merck KGaA, Darmstadt, Germany
,
Herwig Buchholz Merck KGaA, Darmstadt, Germany
&
Burkhard König Institut für Organische Chemie, Universität Regensburg, D-93040, Regensburg, GermanyCorrespondence[email protected]
Pages 1181-1187 | Received 10 May 2001, Published online: 16 Aug 2006
 
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ABSTRACT

Deposition of palladium as a catalyst on polymer beads, such as Merrifield resin or TentaGel, allows the reduction of polymer-bound 4-nitro benzoate to the corresponding anilines with dilute hydrazine hydrate solution in DMF at room temperature.

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