Advanced search
Publication Cover
Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 32, 2002 - Issue 18
Submit an article Journal homepage
57
Views
9
CrossRef citations to date
0
Altmetric
Original Articles

SYNTHESIS OF A NEW CHIRAL o-HYDROXYARYLDIAZAPHOSPHONO- DIAMIDE AS LIGAND CATALYSTS FOR ASYMMETRIC SILYLCYANATION OF AROMATIC ALDEHYDES

Zhuo-Hong Yang Wuhan Insititute of Science and Technology, Wuhan, 430073, P.R. China
,
Zheng-Hong Zhou State Key Laboratory of Elemento-Organic Chemistry, Institute of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071, P.R. China
,
Li-Xin Wang State Key Laboratory of Elemento-Organic Chemistry, Institute of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071, P.R. China
,
Kang-Ying Li State Key Laboratory of Elemento-Organic Chemistry, Institute of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071, P.R. China
,
Qi-Lin Zhou State Key Laboratory of Elemento-Organic Chemistry, Institute of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071, P.R. China
&
Chu-Chi Tang State Key Laboratory of Elemento-Organic Chemistry, Institute of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071, P.R. ChinaCorrespondence[email protected]
Pages 2751-2756 | Received 26 Sep 2001, Published online: 18 Oct 2011
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

ABSTRACT

A new chiral o-hydroxyaryldiazaphosphonodiamide 1 was synthesized from (−)-α-methylbenzylamine, it was found to be efficient ligand for the Ti(O-iPr)4 catalyzed asymmetric trimethylsilylcyanation of aldehydes. Corresponding aromatic cyanohydrins were obtained in good chemical yield and enantiomeric excesses (e.e.s) up to 90%.

ACKNOWLEDGMENT

We are grateful to the National Natural Science Foundation of China (No. 29872016 and 29725204) for the financial support.

Log in via your institution

Access through your institution

Log in to Taylor & Francis Online

Restore content access

Restore content access for purchases made as guest
Purchase options * Save for later

PDF download + Online access

  • 48 hours access to article PDF & online version
  • Article PDF can be downloaded
  • Article PDF can be printed
USD 61.00 Add to cart

Issue Purchase

  • 30 days online access to complete issue
  • Article PDFs can be downloaded
  • Article PDFs can be printed
USD 422.00 Add to cart

* Local tax will be added as applicable

Related Research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.