Advanced search
Publication Cover
Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 32, 2002 - Issue 18
Submit an article Journal homepage
140
Views
18
CrossRef citations to date
0
Altmetric
Original Articles

DEPROTECTION OF 1,1-DIACETATES WITH [NO+ ⋅ CROWN ⋅ H(NO3)2−]

Mohammad Ali Zolfigol Chemistry Department, College of Science, Bu-Ali Sina University, Hamadan, 65174, IranCorrespondence[email protected]
,
Mohammad Hassan Zebarjadian Chemistry Department, College of Science, Bu-Ali Sina University, Hamadan, 65174, Iran
,
Iraj Mohammadpoor-Baltork Chemistry Department, College of Science, Isfahan University, Isfahan, I.R. Iran
&
Mojtaba Shamsipur Chemistry Department, College of Science, Razi University, Kermanshah, Iran
Pages 2803-2808 | Received 26 Jul 2001, Published online: 18 Oct 2011
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

ABSTRACT

An ionic complex has been obtained from N2O4 in the presence of the macrocyclic polyether 18-crown-6. This crystalline compound was used as an effective deprotecting agent for the conversion of 1,1-diacetates to their corresponding aldehydes at room temperature with quantitative yields.

ACKNOWLEDGMENT

The financial support for this work by the research affairs of Bu-Ali Sina University, Hamadan, Iran is acknowledged.

Log in via your institution

Access through your institution

Log in to Taylor & Francis Online

Restore content access

Restore content access for purchases made as guest
Purchase options * Save for later

PDF download + Online access

  • 48 hours access to article PDF & online version
  • Article PDF can be downloaded
  • Article PDF can be printed
USD 61.00 Add to cart

Issue Purchase

  • 30 days online access to complete issue
  • Article PDFs can be downloaded
  • Article PDFs can be printed
USD 422.00 Add to cart

* Local tax will be added as applicable

Related Research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.