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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 32, 2002 - Issue 18
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Original Articles

ALLYLATION OF ESTERS PROMOTED BY METALLIC DYSPROSIUM IN THE PRESENCE OF MERCURIC CHLORIDE

, , &
Pages 2829-2835 | Received 29 Jun 2001, Published online: 18 Oct 2011
 

ABSTRACT

In the presence of mercuric chloride, the reactions of esters with allyl bromide and metallic dysprosium in anhydrous THF give diallyl alkyl carbinols in good yields. When γ-butyrolactone is used as the substrate, the corresponding product is 4-allyl-6-heptene-1, 4-diol.

ACKNOWLEDGMENTS

We thank the National Natural Science Foundation of China (project No. 29872008) for financial support.

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