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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 32, 2002 - Issue 23
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Original Articles

DICHLOROBIS[1,4-DIAZABICYCLO(2,2,2)OCTANE]-(TETRAHYDROBORATO)ZIRCONIUM, [Zr(BH4)2CL2(dabco)2] (ZrBDC), A NEW STABLE, EFFICIENT, AND SELECTIVE REDUCING AGENT

H. Firouzabadi Chemistry Department, College of Sciences, Shiraz University, Shiraz, 71454, IranCorrespondence[email protected]
,
N. Iranpoor Chemistry Department, College of Sciences, Shiraz University, Shiraz, 71454, IranCorrespondence[email protected]
&
H. Alinezhad Chemistry Department, College of Sciences, Shiraz University, Shiraz, 71454, Iran
Pages 3575-3586 | Received 08 Oct 2001, Published online: 16 Aug 2006
 
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ABSTRACT

High yield preparation of a new stable zirconium borohydride, [Zr(BH4)2Cl2(dabco)2] is described and its application for the selective and efficient reduction of aldehydes and ketones is presented.

ACKNOWLEDGMENTS

We are thankful to professor M. Rashidi for useful discussions and also to the Shiraz University Research Council and The Ministry of Science, Research and Technology of Iran for a grant in support of this work.

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