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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 33, 2003 - Issue 1
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Original Articles

Peri and Regioselective Synthesis of New Heterocyclic Compounds from 1,5-Benzodiazepines

S. Elhazazi Laboratoire de Chimie des Substances Naturelles et des Hétérocycles associé au CNCPRST, Département de Chimie, Faculté des Sciences–Semlalia, Université Cadi Ayyad, Marrakech, Maroc
,
A. Baouid Laboratoire de Chimie des Substances Naturelles et des Hétérocycles associé au CNCPRST, Département de Chimie, Faculté des Sciences–Semlalia, Université Cadi Ayyad, Marrakech, Maroc
,
A. Hasnaoui Laboratoire de Chimie des Substances Naturelles et des Hétérocycles associé au CNCPRST, Département de Chimie, Faculté des Sciences–Semlalia, Université Cadi Ayyad, Marrakech, Maroc; Laboratoire de Chimie des Substances Naturelles et des Hétérocycles associé au CNCPRST, Département de Chimie, Faculté des Sciences–Semlalia, Université Cadi Ayyad, BP 2390, 40001, Marrakech, MarocCorrespondence[email protected]
&
P. Compain Institut de Chimie Organique et Analytique UMR 6005 du CNRS, Orléans, France
Pages 19-27 | Received 02 Jan 2002, Published online: 20 Aug 2006
 
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Abstract

Condensation of nitrilimines with 1,5-benzodiazepines was achieved in a one-pot procedure, to give a variety of new heterocyclic compounds. This reaction was found to be completely peri and regioselective. The new structures were elucidated by spectral methods and confirmed by X-ray crystallographic analysis.

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